京都大学/牧准教授らの研究成果がIndustrial & Engineering Chemistry Researchに掲載されました
複合ポリマーナノ粒子の合成と形態制御
− インクジェット混合システムを用いた粒子の合成 −
国立大学法人京都大学 の 准教授 牧 泰輔氏らは、インクジェットヘッド２本を用いて液滴を混合するシステムにより、液滴の衝突速度、衝撃パラメータ、および溶液濃度が合成される複合ポリマーナノ粒子の形態制御に及ぼす影響を明らかにし、ヤヌスナノ粒子の合成に成功しました。
Abstract
Complex polymer nanoparticles were synthesized via a one-step antisolvent precipitation method using an inkjet mixing system. The effect of collision speed, impact parameter, and solution concentration on the product profiles was investigated. Taking advantage of the rapid mixing capability of an inkjet mixing system, the balance of the diffusion and stabilization rate was discussed, and the mechanism of morphology change in complex polymer nanoparticles was suggested. According to the suggested mechanism, it was demonstrated that the morphology was controllable by changing the mixing ratio of solvents and anti-solvents under rapid mixing. It was also demonstrated that the morphology and particle size of the complex polymer nanoparticles were controllable by changing the collision rate, impact parameter, and solution concentration, and Janus polymer nanoparticles were successfully synthesized with dav = 300 nm and CV = 0.2.
Complex polymer nanoparticles were synthesized via a one-step antisolvent precipitation method using an inkjet mixing system. The effect of collision speed, impact parameter, and solution concentration on the product profiles was investigated. Taking advantage of the rapid mixing capability of an inkjet mixing system, the balance of the diffusion and stabilization rate was discussed, and the mechanism of morphology change in complex polymer nanoparticles was suggested. According to the suggested mechanism, it was demonstrated that the morphology was controllable by changing the mixing ratio of solvents and anti-solvents under rapid mixing. It was also demonstrated that the morphology and particle size of the complex polymer nanoparticles were controllable by changing the collision rate, impact parameter, and solution concentration, and Janus polymer nanoparticles were successfully synthesized with dav = 300 nm and CV = 0.2.
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論文情報
| タイトル | Complex Polymer Nanoparticle Synthesis and Morphology Control Using an Inkjet Mixing System |
|---|---|
| 掲載誌 | Industrial & Engineering Chemistry Research |
| 著者 | Taisuke Maki*, Yosuke Muranaka, Saki Takeda, Kazuhiro Mae Department of Chemical Engineering, Kyoto University, Kyoto, Japan |
| 掲載⽇ | 2023年1月5日 |
| DOI | 10.1021/acs.iecr.2c03767 |